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Abstract. Urbanization has a profound influence on regional meteorology and air qualityin megapolitan Southern California. The influence of urbanization onmeteorology is driven by changes in land surface physical properties and landsurface processes. These changes in meteorology in turn influence air qualityby changing temperature-dependent chemical reactions and emissions,gas–particle phase partitioning, and ventilation of pollutants. In this studywe characterize the influence of land surface changes via historicalurbanization from before human settlement to the present day on meteorology andair quality in Southern California using the Weather Research and ForecastingModel coupled to chemistry and the single-layer urban canopy model(WRF–UCM–Chem). We assume identical anthropogenic emissions for thesimulations carried out and thus focus on the effect of changes in landsurface physical properties and land surface processes on air quality.Historical urbanization has led to daytime air temperature decreases of up to1.4 K and evening temperature increases of up to 1.7 K. Ventilation of airin the LA basin has decreased up to 36.6 % during daytime and increasedup to 27.0 % during nighttime. These changes in meteorology are mainlyattributable to higher evaporative fluxes and thermal inertia of soil fromirrigation and increased surface roughness and thermal inertia frombuildings. Changes in ventilation drive changes in hourlyNOx concentrations with increases of up to 2.7 ppb duringdaytime and decreases of up to 4.7 ppb at night. Hourly O3concentrations decrease by up to 0.94 ppb in the morning and increase by upto 5.6 ppb at other times of day. Changes in O3 concentrations aredriven by the competing effects of changes in ventilation and precursorNOx concentrations. PM2.5 concentrations show slightincreases during the day and decreases of up to 2.5 µg m−3at night. Process drivers for changes in PM2.5 include modificationsto atmospheric ventilation and temperature, which impact gas–particle phasepartitioning for semi-volatile compounds and chemical reactions.Understanding process drivers related to how land surface changes effectregional meteorology and air quality is crucial for decision-making on urbanplanning in megapolitan Southern California to achieve regional climateadaptation and air quality improvements. 

In the US, more than 80% of fatal cases of heat exposure are reported in urban areas. Notably, indoor exposure is implicated in nearly half of such cases, and lack of functioning air conditioning (AC) is the predominant cause of overheating. For residents with limited capacity to purchase, maintain, and operate an AC system, or during summertime power outages, the ability of buildings to maintain safe thermal conditions without mechanical cooling is the primary protective factor against heat. In this paper, we use whole-building energy simulations to compare indoor air temperature inside archetypical single-family residential buildings without AC at the start and middle of the century in eight US cities. We ran the models using hourly output from 10 year regional climate simulations that explicitly include heating from mid-century projections of urban development and climate change under a ‘business-as-usual’ emissions scenario. Moreover, to identify the impacts from evolving construction practices, we compare different versions of building energy standards. Our analysis shows that summertime overheat time may increase by up to 25% by the middle of century. Moreover, we find that, while newer building energy codes reduce thermal comfort under moderate outdoor weather, they perform better under extreme heat.